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Redox Systems Under Nano-Space Control

Nano-Space Control and its Applications. Auflage 2006. Book. Sprache: Englisch.
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3.1.1 ?-Conjugated Materials ?-conjugated polymers (CPs) and oligomers are materials with an extended ?-system along the backbone. The materials possess many remarkable prop- ties, including high charge carrier mobilities, electrical conductivities ( … weiterlesen
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Titel: Redox Systems Under Nano-Space Control

ISBN: 3540295798
EAN: 9783540295792
Nano-Space Control and its Applications.
Auflage 2006.
Book.
Sprache: Englisch.
Herausgegeben von Toshikazu Hirao
Springer Berlin Heidelberg

5. April 2006 - gebunden - 316 Seiten

Beschreibung

3.1.1 ?-Conjugated Materials ?-conjugated polymers (CPs) and oligomers are materials with an extended ?-system along the backbone. The materials possess many remarkable prop- ties, including high charge carrier mobilities, electrical conductivities (doped), electrochromism, and electroluminescence [1]. These properties have been taken advantage of in exploration of potential applications including in ch- ical sensors, light-emitting devices, and ?eld-effect transistors. Many efforts have been devoted to synthesizing new conjugated polymers and oligomers in an effort to increase their processibility, optimize the desirable properties, and explore new properties. In Fig. 3.1 are shown examples of some of the CPs that have been prepared and studied. Coupling ?-conjugated materials to metal complexes gives hybrid mate- als in which the properties of the metal complex may be coupled to those of the conjugated backbone [2]. For example, these materials could be used in energy-harvesting devices such as solar cells or polymer-based light-emitting devices,wherehighchargecarrier mobilities of theconjugatedmaterialmay be combined with either the light-absorbing or emitting metal groups, giving improved device performance [3, 4]. In addition to an electronic role, metal complexes may also be used to geometrically orient ?-conjugated materials in speci?c three-dimensional arrangments in the solid state. Careful conside- tion of theelectronicinteractionsand excitedstatesisnecessary for thedesign of functional materials of this type.

Inhaltsverzeichnis

Redox Systems via d,?-Conjugation.
Conjugated Complexes with Quinonediimine Derivatives.
Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathways.
Metal-Containing ?-Conjugated Materials.
Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models for Molecular Wires.
Molecular Metal Wires Built from a Linear Metal Atom Chain Supported by Oligopyridylamido Ligands.
Multielectron Redox Catalysts in Metal-Assembled Macromolecular Systems.
Redox Systems via Coordination Control.
Triruthenium Cluster Oligomers that Show Multistep/Multielectron Redox Behavior.
Molecular Architecture of Redox-Active Multilayered Metal Complexes Based on Surface Coordination Chemistry.
Programmed Metal Arrays by Means of Designable Biological Macromolecules.
Metal-Incorporated Hosts for Cooperative and Responsive Recognition to External Stimulus.
Synthesis of Poly(binaphthol) via Controlled Oxidative Coupling.
Redox Systems via Molecular Chain Control.
Nano Meccano.
Through-Space Control of Redox Reactions Using Interlocked Structure of Rotaxanes.
Metal-Containing Star and Hyperbranched Polymers.
Electronic Properties of Helical Peptide Derivatives at a Single Molecular Level.
Construction of Redox-Induced Systems Using Antigen-Combining Sites of Antibodies and Functionalization of Antibody Supramolecules.
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