Spin-1 NMR

The Basic Physics of Spin-1 Systems.- 1.1 General Introduction.- 1.2 Spin States and Matrix Representations of Operators for Spin-1.- 1.3 Spin-1 Operator Algebra.- 1.4 L wdin Projectors for Spin-1.- 1.5 Interactions Relevant in Spin-1 NMR.- 1.6 Pulse Rotations.- 1.7 Density Matrix Description of the State of Spin-1 Ensembles.- 1.8 Evolution of the Spin-1 System Under Quadrupolar Coupling.- 1.9 Phase Changes of Spin-1 Wavefunctions Under Rotation.- 1.10 Evolution of the Spin-1-Spin-1/2 System Under Scalar Coupling.- 1.11 Spin Tickling in a Spin-l/2-Spin-l Scalar Coupled System.- 1.12 Evolution of the Spin-l-Spin-1 System Under Scalar Coupling.- 1.13 Coherence Transfer Function for Spin-1 Systems.- 1.14 Quadrupolar Relaxation.- 1.15 Spin-1 Behavior of Two Equivalent Spins-1/2.- NMR of Systems Involving Spin-1 Nuclei in the Isotropic Phase..- 2.1 Chemical Shift Information.- 2.2 General Spectral Features Consequent on Coupling to Spin-1.- 2.3 Laboratory Frame Polarization Transfer Involving Spin-1 Nuclei.- 2.4 INEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I).- 2.5 DEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I).- 2.6 Polarization Transfer from Spin-1/2 (I) to Spin-1 (S).- 2.7 Pulse Width Calibration for Polarization Transfer Experiments.- 2.8 Polarization Transfer Between Spin-1 Nuclei.- 2.9 Two-Dimensional Experiments Involving Spin-1 Nuclei.- 2.10 Correlation Spectroscopy (COSY).- 2.11 Heteronuclear Multiple Quantum Spectroscopy.- 2.12 Homonuclear Multiple Quantum Spectroscopy.- 2.13 Relayed Correlation Spectroscopy.- 2.14 Instrumentation for High Resolution Spin-1 NMR.- 3 NMR of Spin-1 Systems in the Solid State.- 3.1 Introduction.- 3.2 Quadrupolar Echo.- 3.3 Jeener-Broekaert Sequence.- 3.4 Deuterium NMR Spectroscopy of Single Crystal Systems.- 3.5 Two-Dimensional Deuterium COSY Spectra in the Solid State.- 3.6 Deuterium NMR Under Magic Angle Spinning.- 3.7 Double Quantum Spectroscopy.- 3.8 QUADSHIFT Experiment.- 3.9 Overtone Spectroscopy.- 3.10 Spin-1/2-Spin-1 Dipolar Coupling.- 3.11 Spin Alignment.- 3.12 Deuterium Exchange Spectroscopy in Single Crystals.- 3.13 Deuterium Exchange Spectroscopy.- 3.14 Spin-1 Double Quantum Imaging.- 3.15 Instrumentation for Solid State NMR.- 4 Reference.

The Basic Physics of Spin-1 Systems. - 1. 1 General Introduction. - 1. 2 Spin States and Matrix Representations of Operators for Spin-1. - 1. 3 Spin-1 Operator Algebra. - 1. 4 Löwdin Projectors for Spin-1. - 1. 5 Interactions Relevant in Spin-1 NMR. - 1. 6 Pulse Rotations. - 1. 7 Density Matrix Description of the State of Spin-1 Ensembles. - 1. 8 Evolution of the Spin-1 System Under Quadrupolar Coupling. - 1. 9 Phase Changes of Spin-1 Wavefunctions Under Rotation. - 1. 10 Evolution of the Spin-1-Spin-1/2 System Under Scalar Coupling. - 1. 11 Spin Tickling in a Spin-l/2-Spin-l Scalar Coupled System. - 1. 12 Evolution of the Spin-l-Spin-1 System Under Scalar Coupling. - 1. 13 Coherence Transfer Function for Spin-1 Systems. - 1. 14 Quadrupolar Relaxation. - 1. 15 Spin-1 Behavior of Two Equivalent Spins-1/2. - NMR of Systems Involving Spin-1 Nuclei in the Isotropic Phase. . - 2. 1 Chemical Shift Information. - 2. 2 General Spectral Features Consequent on Coupling to Spin-1. - 2. 3 Laboratory Frame Polarization Transfer Involving Spin-1 Nuclei. - 2. 4 INEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I). - 2. 5 DEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I). - 2. 6 Polarization Transfer from Spin-1/2 (I) to Spin-1 (S). - 2. 7 Pulse Width Calibration for Polarization Transfer Experiments. - 2. 8 Polarization Transfer Between Spin-1 Nuclei. - 2. 9 Two-Dimensional Experiments Involving Spin-1 Nuclei. - 2. 10 Correlation Spectroscopy (COSY). - 2. 11 Heteronuclear Multiple Quantum Spectroscopy. - 2. 12 Homonuclear Multiple Quantum Spectroscopy. - 2. 13 Relayed Correlation Spectroscopy. - 2. 14 Instrumentation for High Resolution Spin-1 NMR. - 3 NMR of Spin-1 Systems in the Solid State. - 3. 1 Introduction. - 3. 2 Quadrupolar Echo. - 3. 3 Jeener-Broekaert Sequence. - 3. 4 Deuterium NMR Spectroscopy of Single Crystal Systems. -3. 5 Two-Dimensional Deuterium COSY Spectra in the Solid State. - 3. 6 Deuterium NMR Under Magic Angle Spinning. - 3. 7 Double Quantum Spectroscopy. - 3. 8 QUADSHIFT Experiment. - 3. 9 Overtone Spectroscopy. - 3. 10 Spin-1/2-Spin-1 Dipolar Coupling. - 3. 11 Spin Alignment. - 3. 12 Deuterium Exchange Spectroscopy in Single Crystals. - 3. 13 Deuterium Exchange Spectroscopy. - 3. 14 Spin-1 Double Quantum Imaging. - 3. 15 Instrumentation for Solid State NMR. - 4 Reference.