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Inhaltsverzeichnis
of Part B. - 1. Alkylation of Carbon via Enolates and Enamines. - 1. 1. Generation of Carbon Nucleophiles by Proton Abstraction. - 1. 2. Kinetic Versus Thermodynamic Control in Formation of Enolates. - 1. 3. Other Means of Generating Enolates. - 1. 4. Alkylations of Enolates. - 1. 5. Generation and Alkylation of Dianions. - 1. 6. Solvent Effects in Enolate Alkylations. - 1. 7. Oxygen Versus Carbon as the Site of Alkylation. - 1. 8. Alkylations of Aldehydes, Esters, Nitriles, and Nitro Compounds. - 1. 9. The Nitrogen Analogs of Enols and Enolates Enamine Alkylations. - 1. 10. Alkylation of Carbon by Conjugate Addition. - General References. - Problems. - 2. Reactions of Nucleophilic Carbon Species with Carbonyl Groups. - 2. 1. Aldol Condensation. - 2. 2. Related Condensation Reactions. - 2. 3. The Mannich Reaction. - 2. 4. Acylation of Nucleophilic Carbon. - 2. 5. The Wittig Reaction. - 2. 6. Sulfur Ylides as Nucleophiles. - 2. 7. Nucleophilic Addition-Cyclization. - General References. - Problems. - 3. Addition Reactions of Carbon-Carbon Multiple Bonds. - 3. 1. Addition of Hydrogen. - 3. 2. Addition of Hydrogen Halides. - 3. 3. Hydration and Other Acid-Catalyzed Additions. - 3. 4. Oxymercuration. - 3. 5. Addition of Halogens to Olefins. - 3. 6. Addition of Other Electrophilic Reagents. - 3. 7. Electrophilic Substitution Alpha to Carbonyl Groups. - 3. 8. Hydroboration. - 3. 9. Additions to Allenes and Alkynes. - General References. - Problems. - 4. Reduction of Carbonyl and Other Functional Groups. - 4. 1. Hydride-Transfer Reagents. - 4. 2. Hydrogen-Atom Donors. - 4. 3. Dissolving-Metal Reductions. - General References. - Problems. - 5. Organometallic Compounds. - 5. 1. Organic Derivatives of Group I and II Metals. - 5. 2. Organic Derivatives of Group IIb Metals. - 5. 3. Organic Derivatives of Transition Metals. - 5. 4. Catalysis ofRearrangements by Metal Ions and Complexes. - 5. 5. Organometallic Compounds with ? -Bonding. - General References. - Problems. - 6. Cycloadditions and Unimolecular Rearrangements and Eliminations. - 6. 1. Cycloaddition Reactions. - 6. 2. Photochemical Cycloadditions. - 6. 3. SigmatropicRearrangements. - 6. 4. Unimolecular Thermal Elimination Reactions. - General References. - Problems. - 7. Aromatic Substitution Reactions. - 7. 1. Electrophilic Aromatic Substitution. - 7. 2. Nucleophilic Aromatic Substitution. - 7. 3. Substitutions Involving Aryl Free Radicals. - 7. 4. Reactivity of Polycyclic Aromatics. - General References. - Problems. - 8. Reactions Involving Carbenes, Nitrenes, and Other Electron-Deficient Intermediates. - 8. 1. Carbenes. - 8. 2. Nitrenes. - 8. 3. Rearrangements of Electron-Deficient Intermediates. - 8. 4. Fragmentation Reactions. - 8. 5. Some Synthetically Useful Carbonium-Ion Reactions. - General References. - Problems. - 9. Oxidations. - 9. 1. Oxidation of Alcohols to Aldehydes, Ketones, or Carboxylic Acids. - 9. 2. Addition of Oxygen at Carbon-Carbon Double Bonds. - 9. 3. Cleavage of Carbon-Carbon Double Bonds. - 9. 4. Selective Oxidative Cleavages at Other Functional Groups. - 9. 5. Oxidations of Ketones and Aldehydes. - 9. 6. Allylic Oxidation of Olefins. - 9. 7. Oxidations at Unfunctionalized Carbon Atoms. - General References. - Problems. - 10. Multistep Syntheses. - 10. 1. Protective Groups. - 10. 2. Synthetic Equivalent Groups. - 10. 3. Asymmetric Syntheses. - 10. 4. Synthetic Strategy. - General References. - Problems. - 11. Synthesis of Macromolecules. - 11. 1. Polymerization. - 11. 2. Peptide and Protein Synthesis. - 11. 3. Nucleosides, Nucleotides, and Polynucleotides. - General References. - Problems. - References for Problems.
